2-萘甲醛
| 2-萘甲醛 | |
|---|---|
| |
| 识别 | |
| CAS号 | 66-99-9 
|
| 性质 | |
| 化学式 | C11H8O |
| 摩尔质量 | 156.18 g·mol−1 |
| 外观 | 无色晶体[1] |
| 熔点 | 59—61 °C（332—334 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
2-萘甲醛是一种有机化合物，化学式为C11H8O。它最初于1873年由J. P. Battershall通过2-萘甲酸钙和甲酸钙的热分解得到：[2]
它也可以通过2-萘甲醇[3]或2-萘乙烯[4]的氧化反应来制备。
它和丙二酸二甲酯在乙酸-哌啶混合物的催化下反应，可以得到萘-2-亚甲基丙二酸二甲酯。[5]
参考文献
- ^ 1.0 1.1 Kirihara, Masayuki; Noguchi, Takuya; Okajima, Nobuhiro; Naito, Sayuri; Ishizuka, Yuki; Harano, Aiko; Tsukiji, Hiroyuki; Takizawa, Ryu. Deprotection of dithioacetals with 30% hydrogen peroxide catalyzed by tantalum(V) chloride-sodium iodide or niobium(V) chloride-sodium iodide. Tetrahedron, 2012. 68 (5): 1515-1520. doi:10.1016/j.tet.2011.12.012.
- ^ J. P. Battershall. Ueber einige neue Verbindungen der Naphtalingruppe. Justus Liebigs Annalen der Chemie, 1873. 168 (1): 114-126. doi:10.1002/jlac.18731680112
- ^ Fumiya Tobita, Tomohiro Yasukawa, Yasuhiro Yamashitaa and Shū Kobayashi. Aerobic oxidation of alcohols enabled by nitrogen-doped copper nanoparticle catalysts. Catalysis Science & Technology, 2022. 12. 1043-1048. doi:10.1039/D1CY01777B.
- ^ Topi Ghosh, Neha Choudhary, Dr. Shaikh M. Mobin. Design and Synthesis of Silver Decorated Fe3O4 @ Fe Doped CeO2 Core-Shell Ternary Composite as Highly Efficient Nanocatalyst for Selective Oxidation of Alkenes. ChemistrySelect, 2020. 5 (31): 9601-9606. doi:10.1002/slct.202002349.
- ^ Roman A. Novikov, Vladimir P. Timofeev, and Yury V. Tomilov. Stereoselective Double Lewis Acid/Organo-Catalyzed Dimerization of Donor–Acceptor Cyclopropanes into Substituted 2-Oxabicyclo[3.3.0]octanes. J. Org. Chem. 2012, 77, 14, 5993–6006. doi:10.1021/jo300720d.