1-溴十一烷
1-溴十一烷 | |
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别名 | 1-溴正十一烷 正十一烷基溴 |
识别 | |
CAS号 | 693-67-4 ![]() |
SMILES |
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性质 | |
化学式 | C11H23Br |
摩尔质量 | 235.2 g·mol−1 |
密度 | 1.0521 g·cm−3(20 °C)[1] |
熔点 | −9 °C(264 K)[2] |
沸点 | 124.7—125 °C(397.8—398.1 K)(12 Torr)[2] 137—138 °C(410—411 K)(18 Torr)[3] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
1-溴十一烷是一种有机化合物,化学式为C11H23Br。它可由1-十一醇和溴在三苯基膦的存在下于二氯甲烷中反应得到。[4]1-十二烷酸和溴、氧化汞在四氯化碳中回流反应,也可得到1-溴十一烷。[5]它和叠氮化钠在DMF中反应,可以得到正十一烷基叠氮化物。[6]它和三苯基膦反应,得到季𬭸盐十一烷基三苯基溴化𬭸。[7]
参考文献
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- ^ 2.0 2.1 Takao Kaneko, Taihei Ainazaki. On the Preparations and the Melting Points of n Alkyl-bromides. Nippon kagaku zassi. 1955, 76 (3): 281–284 [2021-01-14]. ISSN 0369-5387. doi:10.1246/nikkashi1948.76.281.
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. PMID 25502598. doi:10.1038/srep07449. (原始内容存档于2022-03-04) (英语).
- ^ S. Ravi, K. M. Mathew, V. K. P. Unny, N. Sivaprasad. A facile synthesis of high specific activity sodium [1-14C] lauryl sulphate under microwave irradiation. Journal of Labelled Compounds and Radiopharmaceuticals. 2005-12, 48 (14): 1055–1058 [2021-01-14]. ISSN 0362-4803. doi:10.1002/jlcr.966 (英语).
- ^ Christiane Lang, Kai Pahnke, Claude Kiefer, Anja S. Goldmann, Peter W. Roesky, Christopher Barner-Kowollik. Consecutive modular ligation as an access route to palladium containing polymers. Polymer Chemistry. 2013, 4 (21): 5456 [2021-01-14]. ISSN 1759-9954. doi:10.1039/c3py00648d (英语).
- ^ Qian Yu, Zhu-Jun Yao, Xiao-Guang Chen, Yu-Lin Wu. Total Synthesis of (10 R )- and (10 S )-Corossolin: Determination of the Stereochemistry at C-10 of the Natural Corossolin and the Differential Toxicity toward Cancer Cells Caused by the Configuration at C-10. The Journal of Organic Chemistry. 1999-04, 64 (7): 2440–2445 [2021-01-14]. ISSN 0022-3263. doi:10.1021/jo982241j (英语).