(甲基环戊二烯基)三羰基锰
(甲基环戊二烯基)三羰基锰 | |
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识别 | |
CAS号 | 12108-13-3 ![]() |
性质 | |
化学式 | C9H7MnO3 |
摩尔质量 | 218.09 g·mol−1 |
沸点 | 112 °C(10 mmHg)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
(甲基环戊二烯基)三羰基锰是一种有机锰化合物,化学式为C9H7MnO3。它可由甲基环戊二烯基钠和五羰基溴化锰在四氢呋喃中反应制得。[1]它在一氧化碳气氛中被钠还原,可以得到十羰基二锰。[2]它和三苯基氢化锡反应,可以得到MeC5H4(CO)2Mn(H)SnPh3和MeC5H4(CO)2Mn(SnPh3)2(其中Me为甲基,Ph为苯基)。[3]
参考文献
- ^ 1.0 1.1 Nesmeyanov, A. N.; Anisimov, K. N.; Kolobova, N. E. Synthesis of manganesecyclopentadienyl and -methylcyclopentadienyl tricarbonyl. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1963. 10: 1880. ISSN 0002-3353
- ^ Harold Podall, Albert Giraitis. Reductive Carbonylation Synthesis of Metal Carbonyls. V. Synthesis of Manganese Carbonyl from π-Methylcyclopentadienylmanganese Tricarbonyl. The Journal of Organic Chemistry. 1961-07, 26 (7): 2587–2588 [2023-03-06]. ISSN 0022-3263. doi:10.1021/jo01351a637. (原始内容存档于2023-04-12) (英语).
- ^ Ulrich Schubert, Erika Kunz, Baerbel Harkers, Johannes Willnecker, Juergen Meyer. .eta.2-Coordination of a tin-hydrogen bond to a transition metal. Molecular structure of (.eta.5-MeC5H4)(CO)2Mn(H)SnPh3. Journal of the American Chemical Society. 1989-03, 111 (7): 2572–2574 [2023-03-06]. ISSN 0002-7863. doi:10.1021/ja00189a032. (原始内容存档于2023-04-12) (英语).