氯化六氨合鉑(IV)

氯化六氨合鉑(IV)
	IUPAC名; Hexaammineplatinum(IV) chloride
別名	Platinum hexammine tetrachloride
識別
CAS號	16893-12-2
PubChem	167586
SMILES	N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4];
性質
化學式	H18Cl4N6Pt
摩爾質量	439.08 g·mol−1
外觀	白色固體
熔點	分解
溶解性	soluble in NH3
結構
配位幾何	octahedral
偶極矩	0 D
相關物質
其他陽離子	[Ni(NH3)6]Cl2; [Co(NH3)6]Cl3
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

氯化六氨合鉑(IV)是一種配位化合物，化學式為[Pt(NH₃)₆]Cl₄，它是可溶於水的白色固體。

它和典型的Pt(IV)配合物一樣，其陽離子[Pt(NH₃)₆]⁴⁺具有抗磁性和動力學惰性，不受強酸影響。它可通過氨處理甲胺配合物[Pt(NH₂CH₃)₄Cl₂]Cl₂來製備，^[1]或氯鉑酸鉀和液氨反應得到。^[2]它在二甲基亞碸（DMSO）的水溶液中和二氰合金(I)酸鉀反應，可以結晶出無色的[(NH₂)₂Pt₂(NH₃)₁₀][Au(CN)₂]₆·5.5DMSO·0.5H₂O。^[3]

它具有少見的四價的氨配陽離子，其共軛鹼[Pt(NH₃)₅NH₂]³⁺和[Pt(NH₃)₄(NH₂)₂]²⁺已被報道。^[4]

參考文獻

^ L. N. Essen. Hexaammineplatinum(IV) Chloride. Inorganic Syntheses. Inorganic Syntheses 15. 1974: 93. ISBN 9780470132463. doi:10.1002/9780470132463.ch21.
^ Sharon A. Brawner; Ivan J. B. Lin; Jong-Ho Kim; Grover W. Everett Jr. Synthesis of β-diiminate chelates by condensation of 2,4-pentanedione with Pt(NH3)6Cl4, Pt(en)3Cl4, and Au(en)2Cl3. Crystal and molecular structure of trans-[Pt(NH3)2(2,4-pentanediiminate)2](ClO4)2. Inorg. Chem. 1978, 17, 5, 1304–1308. doi:10.1021/ic50183a040.
^ David M. Pham , Daniel Rios , Marilyn M. Olmstead , Alan L. Balch. Assisted self-association of dicyanoaurate, [Au(CN)2]−, and dicyanoargentate, [Ag(CN)2]−, through hydrogen bonding to metal ammonia complexes. Inorganica Chimica Acta, 2005. 358 (14): 4261-4269. doi:10.1016/j.ica.2005.06.033.
^ B. Klein, L. Heck. Deprotonierung von Komplexliganden. I. Amidoamminkomplexe des Platin(IV). Zeitschrift für anorganische Chemie. 1975, 416 (3): 269–284. doi:10.1002/zaac.19754160311.

[1] L. N. Essen. Hexaammineplatinum(IV) Chloride. Inorganic Syntheses. Inorganic Syntheses 15. 1974: 93. ISBN 9780470132463. doi:10.1002/9780470132463.ch21.

[2] Sharon A. Brawner; Ivan J. B. Lin; Jong-Ho Kim; Grover W. Everett Jr. Synthesis of β-diiminate chelates by condensation of 2,4-pentanedione with Pt(NH3)6Cl4, Pt(en)3Cl4, and Au(en)2Cl3. Crystal and molecular structure of trans-[Pt(NH3)2(2,4-pentanediiminate)2](ClO4)2. Inorg. Chem. 1978, 17, 5, 1304–1308. doi:10.1021/ic50183a040.

[3] David M. Pham , Daniel Rios , Marilyn M. Olmstead , Alan L. Balch. Assisted self-association of dicyanoaurate, [Au(CN)2]−, and dicyanoargentate, [Ag(CN)2]−, through hydrogen bonding to metal ammonia complexes. Inorganica Chimica Acta, 2005. 358 (14): 4261-4269. doi:10.1016/j.ica.2005.06.033.

[4] B. Klein, L. Heck. Deprotonierung von Komplexliganden. I. Amidoamminkomplexe des Platin(IV). Zeitschrift für anorganische Chemie. 1975, 416 (3): 269–284. doi:10.1002/zaac.19754160311.

[1]

[2]

[3]

[4]