對苯二甲醯氯
對苯二甲醯氯 | |
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IUPAC名 Benzene-1,4-dicarbonyl dichloride[1] | |
別名 | Terephthaloyl dichloride[1] 1,4-Benzenedicarbonyl chloride Benzene-1,4-dicarbonyl chloride Terephthalic acid dichloride Terephthaloyl dichloride p-Phthalyl chloride TCL |
識別 | |
CAS號 | 100-20-9 ![]() |
PubChem | 7488 |
ChemSpider | 7207 |
SMILES |
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InChI |
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InChIKey | LXEJRKJRKIFVNY-UHFFFAOYAY |
性質 | |
化學式 | C8H4Cl2O2 |
莫耳質量 | 203.02 g/mol g·mol⁻¹ |
密度 | 1.34 g/cm3 |
熔點 | 80—82 °C(353—355 K)[2] |
沸點 | 265 °C(538 K) |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
對苯二甲醯氯是一種有機化合物,化學式為C8H4Cl2O2。它可由對苯二甲酸和氯化亞碸在N,N-二甲基甲醯胺(或N,N-二甲基乙醯胺[3])的催化下回流反應得到。[4]它在三氯化鋁的催化下和苯反應,生成1,4-二苯甲醯基苯。[5]
參考文獻
- ^ 1.0 1.1 Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014: 797. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069-FP001.
- ^ Phthaloyl chlorides. 1950 GB 644071
- ^ Bhim Bali Prasad, Darshika Jauhari. A dual-template biomimetic molecularly imprinted dendrimer-based piezoelectric sensor for ultratrace analysis of organochlorine pesticides. Sensors and Actuators B: Chemical. 2015-02, 207: 542–551 [2019-11-07]. doi:10.1016/j.snb.2014.10.115. (原始內容存檔於2018-06-24) (英語).
- ^ Subrata Nath, Suraj Kumar Pathak, Joydip De, Santanu Kumar Pal, Ammathnadu S. Achalkumar. Star-shaped π-gelators based on oxadiazole and thiadiazoles: a structure–property correlation. Molecular Systems Design & Engineering. 2017, 2 (4): 478–489 [2019-11-07]. ISSN 2058-9689. doi:10.1039/C7ME00040E (英語).
- ^ Theodore A. Gazis, Ayan Dasgupta, Michael S. Hill, Jeremy M. Rawson, Thomas Wirth, Rebecca L. Melen. Reactions of hydrazones and hydrazides with Lewis acidic boranes. Dalton Transactions. 2019, 48 (33): 12391–12395 [2019-11-07]. ISSN 1477-9226. doi:10.1039/C9DT01359H (英語).