二(三苯基錫基)硫 是一種有機錫化合物 ,化學式為C36 H30 SSn2 ,或簡寫為(Ph3 Sn)2 S。它可由三苯基氯化錫 和硫化鈉 反應製得。[ 2] 在六羰基鉬 存在下,三苯基氫化錫 和二甲基硫代甲醯胺 反應,也能得到二(三苯基錫基)硫。[ 3] 它可用於將羰基 化合物轉化為相應的硫羰基化合物 。[ 4]
參考文獻
^ "Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2022-11-27].
^ Marc Gingras, T. H. Chan, David N. Harpp. New methodologies: fluorodemetalation of organogermanium, -tin, and -lead compounds. Applications with organometallic sulfides to produce highly active anions and spectroscopic evidence for pentavalent intermediates in substitution at tin . The Journal of Organic Chemistry. 1990-03, 55 (7): 2078–2090 [2022-11-27 ] . ISSN 0022-3263 . doi:10.1021/jo00294a021 . (原始內容存檔 於2022-11-27) (英語) .
^ Renzo Arias-Ugarte, Hemant K. Sharma, Alejandro J. Metta-Magaña, Keith H. Pannell. Mo(CO) 6 -Catalyzed Reduction of N , N -Dimethylthioformamide by Silanes, Germanes, and Stannanes (R 3 EH) To Produce Trimethylamine and Group 14 Thioethers (R 3 E–S–ER 3 ) . Organometallics. 2011-12-26, 30 (24): 6506–6509 [2022-11-27 ] . ISSN 0276-7333 . doi:10.1021/om200753t . (原始內容存檔 於2022-11-27) (英語) .
^ K. Steliou, Mohamed Mrani. Reagents for organic synthesis. Tin-assisted sulfuration: a highly potent new method for the conversion of carbonyl units into their corresponding thiocarbonyl analogs . Journal of the American Chemical Society. 1982-06, 104 (11): 3104–3106 [2022-11-27 ] . ISSN 0002-7863 . doi:10.1021/ja00375a027 . (原始內容存檔 於2022-11-27) (英語) .