十羰基二锝是一种有机锝化合物,化学式为Tc2(CO)10。它可由七氧化二锝和一氧化碳反应[2],或高锝酸铵在金属钠的存在下和一氧化碳在加热、加压的条件下反应制得。它和吡啶在室温下缓慢反应,生成Tc2(μ-CO)2(NC5H5)2(CO)6,加热时,吡啶发生邻位金属化,生成Tc2(μ-H)(μ-NC5H4)(NC5H5)2(CO)6。[3]
参考文献
- ^ 1.0 1.1 D. Wallach. Unit cell and space group of technetium carbonyl, Tc 2 (CO) 10. Acta Crystallographica. 1962-10-01, 15 (10): 1058–1058 [2020-12-09]. ISSN 0365-110X. doi:10.1107/S0365110X62002789. (原始内容存档于2020-11-04).
- ^ J. C. Hileman, D. K. Huggins, H. D. Kaesz. TECHNETIUM CARBONYL. Journal of the American Chemical Society. 1961-07, 83 (13): 2953–2954 [2020-12-09]. ISSN 0002-7863. doi:10.1021/ja01474a038. (原始内容存档于2020-05-08) (英语).
- ^ Maaz Zuhayra, Ulf Lützen, Arne Lützen, Laszlo Papp, Eberhard Henze, Gernot Friedrichs, Franz Oberdorfer. C−H Bond Activation of Coordinated Pyridine: Ortho-Pyridyl-Ditechnetiumhydridocarbonyl Metal Cyclus. Crystal Structure and Dynamic Behavior in Solution. Inorganic Chemistry. 2008-11-03, 47 (21): 10177–10182 [2020-12-09]. ISSN 0020-1669. doi:10.1021/ic8015063 (英语).
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