丙三醇-1,2-碳酸酯
Glycerol-1,2-carbonate | |
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别名 | 碳酸甘油酯 |
识别 | |
CAS号 | 931-40-8 |
PubChem | 97944 |
性质 | |
化学式 | C4H6O4 |
摩尔质量 | 118,09 g·mol−1 g·mol⁻¹ |
外观 | 澄清、无色[1]至浅黄色[2]的液体 |
密度 | * 1.40 g·cm−3(25 °C)[1]
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熔点 | |
沸点 | |
溶解性(水) | with water[4] and polar solvents such as alcohols and miscible with Tetrahydrofuran[5] |
蒸气压 | 0.93 Pa(25 °C)[3] |
折光度n D |
* 1,4570 – 1,4610 (20 °C)[2]
|
危险性 | |
NFPA 704 | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
丙三醇-1,2-碳酸酯是丙三醇(甘油)的环状碳酸酯,化学式为C4H6O4。
它和对甲苯磺酰氯在三乙胺存在下反应,可以得到O-对甲苯磺酰基碳酸甘油酯。[8]
参考文献
- ^ 1.0 1.1 1.2 1.3 来源:Sigma-Aldrich Co., product no. {{{id}}} .
- ^ 2.0 2.1 2.2 Entry from Glycerol-1,2-carbonate from TCI Europe, retrieved on {{{Date}}}
- ^ 3.0 3.1 3.2 3.3 Product Safety Summary for Glycerol carbonate (PDF). UBE Chemical Europe, S.A. 2016-01-25 [15 October 2018]. (原始内容 (PDF)存档于2018-11-01).
- ^ 4.0 4.1 4.2 Technical Bulletin JeffsolR Glycerin Carbonate (PDF). Huntsman Corp. 2008 [15 October 2018]. (原始内容 (PDF)存档于2018-12-22).
- ^ K. Lanjekar, V.R. Rathod. Utilization of glycerol for the production of glycerol carbonate through greener route. J. Environ. Chem. Eng. 1. 2013: 1231–1236. doi:10.1016/j.jece.2013.09.015.
- ^ J.I. Garcia, H. Garcia-Marin, E. Pires. Glycerol based solvents: synthesis, properties, and applications. Green Chem. 16. 2014: 1007–1033. doi:10.1039/C3GC41857J.
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被忽略 (帮助) - ^ J.R. Ochoa-Gómez, O. Gómez-Jiménez-Aberasturi, C. Ramiréz-López, M. Belsué. A brief review on industrial alternatives for the manufacturing of glycerol carbonate, a green chemical. Org. Process Res. Dev. 16. 2012: 389–399. doi:10.1021/op200369v.
- ^ Ana-Catarina Simao, Benita Lynikaite-Pukleviciene, Cyril Rousseau, Arnaud Tatibouet, Stephanie Cassel, Algirdas Sackus, Amelia Rauter, Patrick Rollin. 1,2-Glycerol Carbonate: A Versatile Renewable Synthon. Letters in Organic Chemistry. 2006-10-01, 3 (10): 744–748 [2023-03-03]. ISSN 1570-1786. doi:10.2174/157017806779025960.