1,4-苯二硼酸
1,4-苯二硼酸 | |
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別名 | 對苯二硼酸 |
識別 | |
CAS號 | 4612-26-4 ![]() |
性質 | |
化學式 | C6H8B2O4 |
摩爾質量 | 165.75 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1,4-苯二硼酸是一種有機化合物,化學式為C6H8B2O4。它可以1,4-二溴苯、鎂和硼酸三甲酯為原料反應製得。[1]也有文獻報道了通過1,4-二(三甲基錫基)苯和BH3-THF的反應來製備1,4-苯二硼酸。[2]它和溴苯在Pd(II)催化及碳酸鉀存在下反應,可以得到1,1':4',1''-三聯苯。[3]它可以被氫化鋁鋰還原為Li2[H3BC6H4BH3]。[4]
參考文獻
- ^ Kensuke Nakashima, Takeshi Shimizu, Yoshinobu Kamakura, Akira Hinokimoto, Yasutaka Kitagawa, Hirofumi Yoshikawa, Daisuke Tanaka. A new design strategy for redox-active molecular assemblies with crystalline porous structures for lithium-ion batteries. Chemical Science. 2020, 11 (1): 37–43 [2022-06-20]. ISSN 2041-6520. PMC 7067258
. PMID 32190257. doi:10.1039/C9SC04175C (英語).
- ^ Sandra D. Mandolesi, Santiago E. Vaillard, Julio C. Podestá, Roberto A. Rossi. Synthesis of Benzene- and Pyridinediboronic Acids via Organotin Compounds. Organometallics. 2002-10-01, 21 (22): 4886–4888 [2022-06-20]. ISSN 0276-7333. doi:10.1021/om020163r. (原始內容存檔於2022-01-31) (英語).
- ^ Yu-Xin Ye, Wan-Long Liu, Bao-Hui Ye. A highly efficient and recyclable Pd(II) metallogel catalyst: A new scaffold for Suzuki-Miyaura coupling. Catalysis Communications. 2017-01, 89: 100–105 [2022-06-20]. doi:10.1016/j.catcom.2016.10.017. (原始內容存檔於2018-06-29) (英語).
- ^ Audrey Ledoux, Paolo Larini, Christophe Boisson, Vincent Monteil, Jean Raynaud, Emmanuel Lacôte. Polyboramines for Hydrogen Release: Polymers Containing Lewis Pairs in their Backbone. Angewandte Chemie International Edition. 2015-12-21, 54 (52): 15744–15749 [2022-06-20]. ISSN 1433-7851. doi:10.1002/anie.201508395. (原始內容存檔於2022-06-20) (英語).