鎳(III)酸釹是一種無機化合物,化學式為NdNiO3,其中鎳為+3價。[1]它可通過熱解硝酸鎳和硝酸釹的混合物製得。[2][3]它在高溫(950 °C)氮氣中按下式分解:[2]
- 4 NdNiO3 → 2 Nd2NiO4 + 2 NiO + O2
它在160 °C可以被氫化鈉還原為一價鎳化合物NdNiO2。[4]
參考文獻
- ^ T Moriga. Reduction processes of rare-earth nickelate perovskites LnNiO3 (Ln=La, Pr, Nd). Solid State Ionics. 2002-12-02,. 154-155: 251–255 [2022-03-18]. doi:10.1016/S0167-2738(02)00440-X. (原始內容存檔於2022-06-17) (英語).
- ^ 2.0 2.1 John K. Vassiliou, Marc Hornbostel, Robin Ziebarth, F.J. Disalvo. Synthesis and properties of NdNiO3 prepared by low-temperature methods. Journal of Solid State Chemistry. 1989-08, 81 (2): 208–216 [2022-03-18]. doi:10.1016/0022-4596(89)90008-X. (原始內容存檔於2022-05-08) (英語).
- ^ M.T. Escote, A.M.L. da Silva, J.R. Matos, R.F. Jardim. General Properties of Polycrystalline LnNiO3 (Ln=Pr, Nd, Sm) Compounds Prepared through Different Precursors. Journal of Solid State Chemistry. 2000-05, 151 (2): 298–307 [2022-03-18]. doi:10.1006/jssc.2000.8657. (原始內容存檔於2018-06-02) (英語).
- ^ M.A. Hayward, M.J. Rosseinsky. Synthesis of the infinite layer Ni(I) phase NdNiO2+x by low temperature reduction of NdNiO3 with sodium hydride. Solid State Sciences. 2003-06, 5 (6): 839–850 [2022-03-18]. doi:10.1016/S1293-2558(03)00111-0. (原始內容存檔於2022-07-04) (英語).