1-苯乙炔基金剛烷
1-苯乙炔基金剛烷 | |
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別名 | 1-金剛烷基-2-苯基乙炔 |
識別 | |
CAS號 | 74203-39-7 ![]() |
PubChem | 144631 |
SMILES |
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性質 | |
化學式 | C18H20 |
摩爾質量 | 236.35 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
1-苯乙炔基金剛烷是一種有機化合物,化學式為C18H20。它可由1-氟金剛烷和(三甲基矽基乙炔基)苯在三(五氟苯基)鋁催化下反應製得。[1]它和硫在1,2-二氯苯中反應,可以得到1-金剛烷基苯基二硫雜環丁烯。[2]
參考文獻
- ^ Jaiswal, Amit K.; Goh, Kelvin K. K.; Sung, Simon; Young, Rowan D. Aluminum-Catalyzed Cross-Coupling of Silylalkynes with Aliphatic C–F Bonds. Organic Letters (American Chemical Society (ACS)). 2017-03-28, 19 (7): 1934–1937. ISSN 1523-7060. doi:10.1021/acs.orglett.7b00712.
- ^ Choi, Keun Soo; Akiyama, Isao; Hoshino, Masamatsu; Nakayama, Juzo. A Convenient Synthesis of 1,2-Dithietes and 1,2-Dithioxo Compounds Stabilized by Buttressing and Resonance Effects, Respectively, by Sulfuration of Alkynes with Elemental Sulfur. Bulletin of the Chemical Society of Japan (The Chemical Society of Japan). 1993, 66 (2): 623–629. ISSN 0009-2673. doi:10.1246/bcsj.66.623.