二叔丁基碳二亞胺
二叔丁基碳二亞胺 | |
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別名 | N,N'-二叔丁基碳二亞胺 |
識別 | |
CAS號 | 691-24-7 ![]() |
SMILES |
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性質 | |
化學式 | C9H18N2 |
摩爾質量 | 154.25 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
二叔丁基碳二亞胺是一種有機化合物,化學式為C9H18N2,它可以N,N'-二叔丁基硫脲為原料合成得到。[1]
反應
二叔丁基碳二亞胺在三氟甲磺酸鋅[2]或三甲基鋁[3]催化下,可以和苯胺反應,生成N,N'-二叔丁基-N''-苯基胍。它和草酰氯在二氯甲烷中反應,可以得到2,2-二氯-1,3-二叔丁基-4,5-咪唑烷二酮。[4]
參考文獻
- ^ Kim, Sunggak; Yi, Kyu Yang. 1,1'-Thiocarbonyldi-2,2'-pyridone. A new useful reagent for functional group conversions under essentially neutral conditions. Journal of Organic Chemistry, 1986. doi:10.1021/jo00363a046.
- ^ Li, Dongzhen; Guang, Jie; Zhang, Wen-Xiong; Wang, Yang; Xi, Zhenfeng. Zn(OTf)2-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species. Organic & Biomolecular Chemistry, 2010. doi:10.1039/b923249b.
- ^ Zhang, Wen-Xiong; Li, Dongzhen; Wang, Zitao; Xi, Zhenfeng. Alkyl Aluminum-Catalyzed Addition of Amines to Carbodiimides: A Highly Efficient Route to Substituted Guanidines. Organometallics, 2009. doi:10.1021/om801035t.
- ^ Moerdyk, Jonathan P.; Bielawski, Christopher W. Reductive generation of stable, five-membered N,N'-diamidocarbenes. Chemical Communications, 2014. doi:10.1039/c4cc00846d.