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1-溴-1-甲基環己烷

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1-溴-1-甲基環己烷
識別
CAS號 931-77-1  checkY
PubChem 12502129
SMILES
 
  • BrC1(C)CCCCC1
性質
化學式 C7H13Br
摩爾質量 177.08 g·mol−1
沸點 42 °C(15 mmHg)
79 °C(38 mmHg)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

1-溴-1-甲基環己烷是一種有機化合物,化學式為C7H13Br,它是溴甲基環己烷同分異構體之一。

合成

1-溴-1-甲基環己烷可由1-甲基環己烯氫溴酸反應得到,吸附劑使用硅膠[2]它也可由甲基環己烷在紫外線照射下反應得到。[3]

參考文獻

  1. ^ G. F. Dvorko, I. V. Koshchii, E. A. Ponomareva. Kinetics and mechanism of unimolecular heterolysis of cage-like compounds: XIX. Effect of the nucleofuge nature on the activation parameters of heterolysis of 1-halo-1-methylcyclohexanes in cyclohexane. Heterolysis rate ratio in aprotic and protic solvents. Russian Journal of Organic Chemistry. 2007-01, 43 (1): 50–55 [2023-02-17]. ISSN 1070-4280. doi:10.1134/S1070428007010046 (英語). 
  2. ^ Kiyoshi Tanemura. Silica gel-mediated hydrohalogenation of unactivated alkenes using hydrohalogenic acids under organic solvent-free conditions. Tetrahedron Letters. 2018-12, 59 (49): 4293–4298 [2023-02-17]. doi:10.1016/j.tetlet.2018.10.043. (原始內容存檔於2022-10-23) (英語). 
  3. ^ Manabe, Yoshiyuki; Kitawaki, Yuriko; Nagasaki, Masahiro; Fukase, Koichi; Matsubara, Hiroshi; Hino, Yoshiko; Fukuyama, Takahide; Ryu, Ilhyong. Revisiting the Bromination of C-H Bonds with Molecular Bromine by Using a Photo-Microflow System. Chemistry - A European Journal (Wiley). 2014-08-29, 20 (40): 12750–12753. ISSN 0947-6539. doi:10.1002/chem.201402303.