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三硫代硼酸三苯酯

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三硫代硼酸三苯酯
識別
CAS號 1041-16-3  checkY
性質
化學式 C18H15BS3
摩爾質量 338.32 g·mol−1
熔點 57 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

三硫代硼酸三苯酯是一種有機化合物,化學式為C18H15BS3。它可以苯硫酚三氯化硼為原料反應製得。[2]它和環戊烯-3-酮反應,可以得到1,3-二苯硫基環戊烯。[3]它和HNi(dmpe)2反應,可以得到三乙胺苯硫基硼烷。[4]

參考文獻

  1. ^ J. C. Lockhart. 229. Mechanism of substitution at a boron atom. Part I. Journal of the Chemical Society (Resumed). 1962: 1197 [2022-03-19]. ISSN 0368-1769. doi:10.1039/jr9620001197 (英語). 
  2. ^ Michael T. Mock, Robert G. Potter, Donald M. Camaioni, Jun Li, William G. Dougherty, W. Scott Kassel, Brendan Twamley, Daniel L. DuBois. Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX 3 Compounds. Journal of the American Chemical Society. 2009-10-14, 131 (40): 14454–14465 [2022-03-19]. ISSN 0002-7863. doi:10.1021/ja905287q. (原始內容存檔於2022-03-19) (英語). 
  3. ^ Theodore Cohen, David A. Bennett, Albert J. Mura. Preparative methods for .beta.-acyl vinyl anion equivalents from enones or allyl sulfides. The Journal of Organic Chemistry. 1976-07, 41 (14): 2506–2507 [2022-03-19]. ISSN 0022-3263. doi:10.1021/jo00876a041. (原始內容存檔於2022-03-19) (英語). 
  4. ^ Michael T. Mock, Robert G. Potter, Molly J. O』Hagan, Donald M. Camaioni, William G. Dougherty, W. Scott Kassel, Daniel L. DuBois. Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX3 Compounds. Inorganic Chemistry. 2011-12-05, 50 (23): 11914–11928 [2022-03-19]. ISSN 0020-1669. doi:10.1021/ic200857x.