5-苯基-8-羟基喹啉
5-苯基-8-羟基喹啉 | |
---|---|
![]() | |
识别 | |
CAS号 | 15657-87-1 ![]() |
性质 | |
化学式 | C15H11NO |
摩尔质量 | 221.25 g·mol−1 |
外观 | 白色晶体[1] |
熔点 | 88—90 °C(361—363 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
5-苯基-8-羟基喹啉是一种有机化合物,化学式为C15H11NO。它可由8-甲氧基喹啉和NBS溴代后,与苯硼酸在四(三苯基膦)钯催化下偶联得到。[2]它和五甲基环戊二烯基二氯化铱二聚体反应,可以得到橙色的五甲基环戊二烯基(5-苯基喹啉-8-氧基)氯化铱(III)。[3]
参考文献
- ^ 1.0 1.1 Radek Pohl, Victor A. Montes, Joseph Shinar, Pavel Anzenbacher. Red−Green−Blue Emission from Tris(5-aryl-8-quinolinolate)Al(III) Complexes. The Journal of Organic Chemistry. 2004-03-01, 69 (5): 1723–1725 [2023-03-03]. ISSN 0022-3263. doi:10.1021/jo035602q (英语).
- ^ Mirja Md Mahamudul Hassan, Md Emdadul Hoque, Sayan Dey, Saikat Guria, Brindaban Roy, Buddhadeb Chattopadhyay. Iridium-Catalyzed Site-Selective Borylation of 8-Arylquinolines. Synthesis. 2021-09, 53 (18): 3333–3342 [2023-03-03]. ISSN 0039-7881. doi:10.1055/a-1506-3884 (英语).
- ^ Yeongyu Hwang, Hoimin Jung, Euijae Lee, Dongwook Kim, Sukbok Chang. Quantitative Analysis on Two-Point Ligand Modulation of Iridium Catalysts for Chemodivergent C–H Amidation. Journal of the American Chemical Society. 2020-05-13, 142 (19): 8880–8889 [2023-03-03]. ISSN 0002-7863. doi:10.1021/jacs.0c02079 (英语).