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2,5-二甲基四氢呋喃

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2,5-二甲基四氢呋喃
识别
CAS号 1003-38-9  checkY
SMILES
 
  • O1C(C)CCC1C
性质
化学式 C6H12O
摩尔质量 100.16 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

2,5-二甲基四氢呋喃是一种有机化合物,化学式为C6H12O。它可由2,5-己二醇苯磺酰氯吡啶反应制得,[1]或由2,5-己二酮在催化下氢化得到。[2][3]它和三乙基硅烷三(五氟苯基)硼催化下反应,可以得到三乙基(1-甲基戊氧基)硅烷。[4]

参考文献

  1. ^ Binch, H. (2001). Benzenesulfonyl Chloride. Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289x.rb022
  2. ^ Grochowski, Matthew R.; Yang, Weiran; Sen, Ayusman. Mechanistic Study of a One-Step Catalytic Conversion of Fructose to 2,5-Dimethyltetrahydrofuran. Chemistry - A European Journal, 2012. 18 (39). doi:10.1002/chem.201201522.
  3. ^ Hua, Manli; Song, Jinliang; Huang, Xin; Hou, Minqiang; Fan, Honglei; Zhang, Zhaofu; Wu, Tianbin; Han, Buxing. Support Effect of Ru Catalysts for Efficient Conversion of Biomass-Derived 2,5-Hexanedione to Different Products. ACS Catalysis, 2021. 11 (13). doi:10.1021/acscatal.1c00971.
  4. ^ Gevorgyan, Vladimir; Rubin, Michael; Benson, Sharonda; Liu, Jian-Xiu; Yamamoto, Yoshinori. A Novel B(C6F5)3-Catalyzed Reduction of Alcohols and Cleavage of Aryl and Alkyl Ethers with Hydrosilanes. Journal of Organic Chemistry, 2000. 65 (19). doi:10.1021/jo000726d.