2,2,3-三甲基戊烷

2,2,3-三甲基戊烷
别名	2-叔丁基丁烷
识别
CAS号	564-02-3 ; 40824-48-4（S） ; 54665-47-3（R）
性质
化学式	C8H18
摩尔质量	114.23 g·mol−1
密度	0.71207 g·cm−3
熔点	−112.2 °C（161.0 K）
沸点	110.2 °C（383.3 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2,2,3-三甲基戊烷是一种有机化合物，化学式为 ${\ce {C8H18}}$ ，是辛烷的同分异构体之一。它可由2-甲基丙烷和2-丁烯在催化剂的存在下反应得到。^[4]3,3-二甲基-2-丁酮和乙基溴化镁的反应也能制得2,2,3-三甲基戊烷。^[5]它的性质和2,3,3-三甲基戊烷相似，它们之间难以分离。^[3]

参考文献

^ A.F. Forziati, A.R. Glasgow, C.B. Willingham, F.D. Rossini. Purification and properties of 29 paraffin, 4 alkylcyclopentane, 10-alkylcyclohexane, and 8 alkylbenzene hydrocarbons (PDF). Journal of Research of the National Bureau of Standards. 1946-02, 36 (2): 129 [2020-06-19]. ISSN 0091-0635. doi:10.6028/jres.036.005. （原始内容存档 (PDF)于2018-06-05）（英语）.
^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-06-05]
^ ^3.0 ^3.1 K. C. Laughlin, Frank C. Whitmore. THE TRIMETHYLPENTANES. Journal of the American Chemical Society. 1933-06, 55 (6): 2607–2608 [2020-06-19]. ISSN 0002-7863. doi:10.1021/ja01333a509 （英语）.
^ Parputc, Oleg I.; Zernov, Petr A. Process of alkylation of isobutane with olefins in presence of solid acid catalyst. 2018. US 20180065900 A1.
^ Pierre Lachance, Arthur M. Eastham. The sec -butyl cation; reaction with 2-butene. Canadian Journal of Chemistry. 1981-09-01, 59 (17): 2621–2628 [2020-06-19]. ISSN 0008-4042. doi:10.1139/v81-378 （英语）.

[1] A.F. Forziati, A.R. Glasgow, C.B. Willingham, F.D. Rossini. Purification and properties of 29 paraffin, 4 alkylcyclopentane, 10-alkylcyclohexane, and 8 alkylbenzene hydrocarbons (PDF). Journal of Research of the National Bureau of Standards. 1946-02, 36 (2): 129 [2020-06-19]. ISSN 0091-0635. doi:10.6028/jres.036.005. （原始内容存档 (PDF)于2018-06-05）（英语）.

[2] "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-06-05]

[Laughlin-3] 3.0 ^3.1 K. C. Laughlin, Frank C. Whitmore. THE TRIMETHYLPENTANES. Journal of the American Chemical Society. 1933-06, 55 (6): 2607–2608 [2020-06-19]. ISSN 0002-7863. doi:10.1021/ja01333a509 （英语）.

[4] Parputc, Oleg I.; Zernov, Petr A. Process of alkylation of isobutane with olefins in presence of solid acid catalyst. 2018. US 20180065900 A1.

[5] Pierre Lachance, Arthur M. Eastham. The sec -butyl cation; reaction with 2-butene. Canadian Journal of Chemistry. 1981-09-01, 59 (17): 2621–2628 [2020-06-19]. ISSN 0008-4042. doi:10.1139/v81-378 （英语）.

[1]

[2]

[3]

[4]

[5]