1,2-二苯基乙酮
| 1,2-二苯基乙酮 | |
|---|---|
| |
| 别名 | 脱氧安息香 二苯乙酮 |
| 识别 | |
| CAS号 | 451-40-1 
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| SMILES |
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| 性质 | |
| 化学式 | C14H12O |
| 摩尔质量 | 196.24 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
1,2-二苯基乙酮是一种有机化合物，化学式为C14H12O。它可由安息香[1]或二苯基乙二酮[2]脱氧得到。它和1,2-二溴苯在碳酸铯、三苯基膦和乙酸钯存在下反应，可以得到2,3-二苯基苯并呋喃。[3]
参考文献
- ^ Uranga, Jorge G.; Chiosso, Antonella F.; Santiago, Ana N. One-step selective deoxygenation of alcohols from acyloins. RSC Advances, 2013. doi:10.1039/c3ra40343b.
- ^ Lin, Wei; Hu, Ming-Hua; Feng, Xian; Fu, Lei; Cao, Cheng-Pao; Huang, Zhi-Bin; Shi, Da-Qing. Selective reduction of carbonyl groups in the presence of low-valent titanium reagents. Tetrahedron Letters, 2014. doi:10.1016/j.tetlet.2014.02.072.
- ^ Terao, Yoshito; Satoh, Tetsuya; Miura, Masahiro; Nomura, Masakatsu. Palladium-Catalyzed Cross-Coupling of Benzyl Ketones and α,β-Unsaturated Carbonyl and Phenolic Compounds with o-Dibromobenzenes to Produce Cyclic Products. Bulletin of the Chemical Society of Japan, 1999. doi:10.1246/bcsj.72.2345.