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(2-硝基丙烯基)苯

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(2-硝基丙烯基)苯
IUPAC名
(2-Nitroprop-1-en-1-yl)benzene
别名 P2NP
1-苯基-2-硝基丙烯
β-甲基-β-硝基苯乙烯
β-硝基丙烯基苯
识别
CAS号 705-60-2  checkY
PubChem 1549520
ChemSpider 1266396
SMILES
 
  • [O-][N+](=O)/C(=C/c1ccccc1)C
InChI
 
  • 1/C9H9NO2/c1-8(10(11)12)7-9-5-3-2-4-6-9/h2-7H,1H3/b8-7+
InChIKey WGSVFWFSJDAYBM-BQYQJAHWBX
性质
化学式 C9H9NO2
摩尔质量 163.17 g mol−1 g·mol⁻¹
外观 固体
熔点 65—66 °C(338—339 K)[1]
危险性
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中有害物质的标签图案
GHS提示词 警告
H-术语 H302, H315, H319, H335
P-术语 P261, P264, P280, P301+312, P312, P302+352, P304+340, P305+351+338, P330, P332+313, P337+313
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

(2-硝基丙烯基)苯是一种有机化合物,化学式为C9H9NO2。它可由苯甲醛硝基乙烷在催化下反应制得。[2]在不同的反应条件下,它还原可以得到(2-硝基丙基)苯[3]苯基丙酮[4]、苯基丙酮肟[5]苯丙胺[6]

参考文献

  1. ^ Gordon A. Alles. dl-BETA-PHENYLISOPROPYLAMINES. Journal of the American Chemical Society. 1932-01, 54 (1): 271–274 [2022-03-15]. ISSN 0002-7863. doi:10.1021/ja01340a040. (原始内容存档于2022-03-15) (英语). 
  2. ^ Kantam, M. Lakshmi; Sreekanth, P. One-pot synthesis of conjugated nitroalkenes by diamino-functionalized mesoporous material. Catalysis Letters. 1999. 57 (4): 227-231. ISSN 1011-372X.
  3. ^ Dong Xu, Yang Chen, Changmeng Liu, Jiaxi Xu, Zhanhui Yang. Iridium-catalyzed highly chemoselective and efficient reduction of nitroalkenes to nitroalkanes in water. Green Chemistry. 2021, 23 (16): 6050–6058 [2022-03-15]. ISSN 1463-9262. doi:10.1039/D1GC01907D (英语). 
  4. ^ J.M. Aizpurua, M. Oiarbide, C. Palomo. Reduction of α,β-unsaturated nitrocompounds with tributyltin hydride.. Tetrahedron Letters. 1987-01, 28 (44): 5365–5366 [2022-03-15]. doi:10.1016/S0040-4039(00)96731-5. (原始内容存档于2019-07-19) (英语). 
  5. ^ Yujing Ren, Haisheng Wei, Guangzhao Yin, Leilei Zhang, Aiqin Wang, Tao Zhang. Oxygen surface groups of activated carbon steer the chemoselective hydrogenation of substituted nitroarenes over nickel nanoparticles. Chemical Communications. 2017, 53 (12): 1969–1972 [2022-03-15]. ISSN 1359-7345. doi:10.1039/C6CC08505A (英语). 
  6. ^ Andersson, Sven Goran Berttil; Holmberg, Hans Viktor; Nilsson, Lars Anders Ragnar. Arylethylamines. 1984 GB 2122617 A.