顺丁烯二腈二硫醇镍四乙基铵

顺丁烯二腈二硫醇镍四乙基铵
别名	顺丁烯二腈二硫醇镍(II)二(四乙基铵); 四乙基马来腈二硫醇镍铵
识别
CAS号	15665-90-4
性质
密度	1.286 g·cm−3
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

顺丁烯二腈二硫醇镍四乙基铵是一种配位化合物，化学式为[N(C₂H₅)₄]₂[Ni(C₄N₂S₂)₂]。它是三斜晶系晶体，空间群P1，晶胞参数a=7.5608，b=8.7017，c=12.626 Å，α=93.73，β=104.27，γ=75.257°，Z=1。^[1]它和硫酸银在膦配体的存在下反应，可以得到[Ag(PR₃)₂]₂[Ni(C₄N₂S₂)₂]。^[2]

三价镍化合物[N(C₂H₅)₄][Ni(C₄N₂S₂)₂]是已知的。^[3]

参考文献

^ C. Mahadevan, M. Seshasayee, A. Radha, P. T. Manoharan. Structure of bis(tetraethylammonium) bis[dimercaptomaleodinitrilato(2–)-S,S']nickelate(II), [N(C2H5)4]2[Ni(C4N2S2)2]. Acta Crystallographica Section C Crystal Structure Communications. 1984-12-15, 40 (12): 2032–2034 [2021-08-24]. doi:10.1107/S0108270184010519. （原始内容存档于2021-08-24）.
^ Kyoung-Tae Youm, Youngmee Kim, Youngkyu Do, Moo-Jin Jun. Design and properties of mixed metal multinuclear molecules. Inorganica Chimica Acta. 2000-12, 310 (2): 203–209 [2021-08-24]. doi:10.1016/S0020-1693(00)00284-X. （原始内容存档于2020-02-09）（英语）.
^ P. Kuppusamy, P. T. Manoharan, C. Mahadevan, M. Seshasayee. Crystal and molecular structure ofN-methylphenazinium bis(maleodinitriledithiolato)nickelate(III), [NMP]+ [Ni(mnt)2]?. Journal of Crystallographic and Spectroscopic Research. 1985-08, 15 (4): 359–376 [2021-08-24]. ISSN 0277-8068. doi:10.1007/BF01160728 （英语）.

[1] C. Mahadevan, M. Seshasayee, A. Radha, P. T. Manoharan. Structure of bis(tetraethylammonium) bis[dimercaptomaleodinitrilato(2–)-S,S']nickelate(II), [N(C2H5)4]2[Ni(C4N2S2)2]. Acta Crystallographica Section C Crystal Structure Communications. 1984-12-15, 40 (12): 2032–2034 [2021-08-24]. doi:10.1107/S0108270184010519. （原始内容存档于2021-08-24）.

[2] Kyoung-Tae Youm, Youngmee Kim, Youngkyu Do, Moo-Jin Jun. Design and properties of mixed metal multinuclear molecules. Inorganica Chimica Acta. 2000-12, 310 (2): 203–209 [2021-08-24]. doi:10.1016/S0020-1693(00)00284-X. （原始内容存档于2020-02-09）（英语）.

[3] P. Kuppusamy, P. T. Manoharan, C. Mahadevan, M. Seshasayee. Crystal and molecular structure ofN-methylphenazinium bis(maleodinitriledithiolato)nickelate(III), [NMP]+ [Ni(mnt)2]?. Journal of Crystallographic and Spectroscopic Research. 1985-08, 15 (4): 359–376 [2021-08-24]. ISSN 0277-8068. doi:10.1007/BF01160728 （英语）.

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