乙酰乙酸环己酯
乙酰乙酸环己酯 | |
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识别 | |
CAS号 | 6947-02-0 ![]() |
性质 | |
化学式 | C10H16O3 |
摩尔质量 | 184.23 g·mol−1 |
熔点 | 190—192 °C(463—465 K)[1] |
沸点 | 130—131 °C(403—404 K)(16 torr)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
乙酰乙酸环己酯是一种有机化合物,化学式为C10H16O3。它可由乙酰乙酸甲酯或乙酰乙酸乙酯在催化下和环己醇反应制得。[3][4]它和苯乙炔在碳酸银、乙酸钾存在下反应,可以得到2-甲基-5-苯基-3-呋喃甲酸环己酯。[5]它和氯化镁反应,形成配合物。[6]
参考文献
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- ^ Chuan He, Sheng Guo, Jie Ke, Jing Hao, Huan Xu, Hongyi Chen, Aiwen Lei. Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans. Journal of the American Chemical Society. 2012-04-04, 134 (13): 5766–5769 [2021-11-20]. ISSN 0002-7863. doi:10.1021/ja301153k. (原始内容存档于2021-11-20) (英语).
- ^ L.I. Koval, V.I. Dzyuba, V.V. Bon, O.L. Ilnitska, V.I. Pekhnyo. Synthesis and structure of anhydrous complexes of magnesium(II) with β-ketoesters of higher alcohols. Polyhedron. 2009-09, 28 (13): 2698–2702 [2021-11-20]. doi:10.1016/j.poly.2009.05.034. (原始内容存档于2022-03-22) (英语).