高氯酸釓 是一種無機化合物 ,化學式為Gd(ClO4 )3 。它可由氧化釓 和高氯酸 (70~72%)在80 °C反應得到。[ 1] 它可以和二噁烷形成無色的Gd(ClO4 )3 ·9H2 O·4C4 H8 O2 配合物晶體。[ 2] 它和myo-肌醇、乙酸鈉 、氫氧化鈉 反應,可以得到含巨型分子簇{Gd140 }的配合物。[ 1] 它和氯化鉻 、2,2'-聯吡啶 在pH=5.1下反應,可以得到[GdCr(bipy)2 (OH)2 (H2 O)6 ](ClO4 )4 ·2H2 O。[ 3]
參考文獻
^ 1.0 1.1 Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng. A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family . Journal of the American Chemical Society. 2017-12-20, 139 (50): 18178–18181 [2023-03-15 ] . ISSN 0002-7863 . doi:10.1021/jacs.7b11112 . (原始內容存檔 於2023-03-15) (英語) .
^ Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto. The reaction of dioxane with the perchlorate hydrates of a few transition metals. Chemische Berichte , 1961. 94: 1153-1155.
^ Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun. Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand . European Journal of Inorganic Chemistry. 2015-12, 2015 (34): 5702–5707 [2023-03-15 ] . ISSN 1434-1948 . doi:10.1002/ejic.201500786 (英語) .